产品编号
1169913
CAS 号
7677-24-9
中文名称
三甲基氰硅烷
MDL 号
MFCD00001765
分子量
99.21
存储条件
-20°C
网页展示纯度为入库指导纯度值,各批次间存在一定差异,实际纯度以收货为准
熔点
11-12 °C
沸点
114-117 °C at 760 mmHg
闪点
1.1°C
旋光
描述
TPSA
23.79
LogP
1.38738
H_Acceptors
1
H_Donors
0
Rotatable_Bonds
0
[1]. G K Surya Prakash, et al. Effect of carbonates/phosphates as nucleophilic catalysts in dimethylformamide for efficient cyanosilylation of aldehydes and ketones. Proc Natl Acad Sci U S A. 2007 Feb 27;104(9):3026-30.
[2]. Guang-Wu Zhang, et al. Br?nsted acid-catalyzed efficient Strecker reaction of ketones, amines and trimethylsilyl cyanide. Org Biomol Chem. 2010 Mar 21;8(6):1399-405.
[3]. Jun Wang, et al. Asymmetric activation of tropos 2,2'-biphenol with cinchonine generates an effective catalyst for the asymmetric strecker reaction of N-tosyl-protected aldimines and ketoimines. Angew Chem Int Ed Engl. 2007;46(44):8468-70.
[4]. Ke Shen, et al. Facile and efficient enantioselective Strecker reaction of ketimines by chiral sodium phosphate. Chemistry. 2009 Jun 8;15(24):6008-14.
[5]. Mikhail D Kosobokov, et al. Difluoro(trimethylsilyl)acetonitrile: synthesis and fluoroalkylation reactions. J Org Chem. 2012 Jul 6;77(13):5850-5.
警示图
警示词
Danger
危险申明
H225-H300+H310+H330-H410
警告申明
P210-P233-P240-P241-P242-P243-P260-P262-P264-P270-P271-P273-P280-P284-P302+P352-P304+P340-P330-P361+P364-P370+P378-P391-P405-P501
GHS 编码
GHS02,GHS06,GHS09
危险类别
6.1
UN 编码
3384
包装等级
Ⅰ
现货供应
专业护航
售后无忧
品质保障
无需凑单